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The Rujm el-Hili, built around 5000 years ago, is believed to be used as a calendar device to mark the winter and summer solstices. The sunrise can be seen from the center of the entranceway during the summer and winter solstices, while holes in the wall will line up with the sun during the fall and spring equinoxes. It is believed that the structure, which is nine rings of rocks stacked about eight feet high, pointed towards stars and helped sheep herders predict the rainy seasons. Foucault’s pendulum demonstrates Earth’s rotation by changing angles in it’s produced lines. As the suspended weight swings back and forth, it would pour sand out of the pointed end at the bottom. The sand would follow the direction of the swinging and would change angles over time, eventually creating a circle. The change in angles implies that the earth is moving below it. At least 18 alignments of astrological bodies have been confirmed in the walls of the temple. During the Spring Equinox, the sun rises over the central tower. Using the Cambodian measurement of a hit, certain measurements of the temple are significant astrological signs, as the temple measures 189 hats and 176 hats adding up to 365, the number of days in a year. Measurements in the temple also include steps being 12 hats for 12 lunar cycles, and a tower being 91 hats for the days between solstices and equinoxes. Lengths of door ways in the temple are around 27 and 28 hats, being close to the number of days the moon takes to orbit. Synthesis of Alum Abstract Alum is a hydrated double sulfate. It has many uses in world and is even used in everyday items. Alum can be made from a simple lab experiment from aluminum and a couple chemicals. Introduction Alum is any compound with the empirical formula of AB(SO4)2·12H2O, such as Sodium Alum NaAl(SO4)2·12H2O, Ammonium Alum N4Al(SO4)2·12H2O, Chrome Alum KCr(SO4)2·12H2O, and the most common Potassium Alum KAl(SO4)2·12H2O [2]. Potassium alum is known to the baking world as tawas or potash alum. Potassium alum is used in baking for baking powder and for pickling. It is also used in a few industrial processes, such as tanning leather, dying, and as a flocculant to clarify turbid liquids [3]. Potassium alum is also used in vaccines for hepatitis, treating infections and wounds, used in toothpaste, purifying piped water, uses in deodorants, and as a fireproofing agent in cloths [3]. Since before 2000 B.C., the ancient civilization of Mesopotamia was known to had imported large quantities of alum from ancient Egypt. The Mesopotamians would use the alum to make dye madder fixed to textiles. The Egyptians would mine alum in their oases of Kharga and Dakhla, they didn’t start using it for almost one thousand years later to glaze ceramics, make glass, and dye their fabrics. The Egyptians would also sell alum to the Greek and Roman empires. In 545 BC when the temple of Delphi was destroyed Egypt sent alum over to repair it [1]. To the Chinese, alum would be essential to their alchemist’s lab, they would use it to brew elixirs. In ancient Rome, the Romans also used alum to dye cloth and to preserve leather. The alum was important because the color of the dye it bonded to the cloth symbolized power. Romans also used alum for medicine. After Constantinople fell and an alum trading point was gone, a man by the name of John de Castro went to the Pope and told him the secret of alum making. When alunite was found in Tolfa the Pope, Nicholas V, soon turned alunite in a monopoly. In Britain, during the time of Henry VIII’s reign (1509-1547), they began to search for a reliable, cheaper, and local source of alum. They didn’t end up finding any until the early 1600’s [1]. Purpose During this experiment, new information and chemistry skills were learned. The purpose was to obtain the knowledge and experience of synthesizing alum from a piece of aluminum. Procedure To conduct this lab, you will need the following supplies: aluminum, 4M KOH, 6M H2SO4, 50% Ethanol, 150mL Beaker, a Funnel, Filter Paper, Ice, Thermometer, Hot Plate, (INSERT MORE HERE). To start, one will need to cut a gram of aluminum from a sheet of aluminum foil. Once that is done, you would need to tear the foil into pieces and place them in a 150mL beaker. When the shredded aluminum pieces are in, you would pour in 25mL of 4M KOH. A reaction will occur, once it has finished you would gravity filter the solution to remove impurities. Keeping the clear solution, you will want to have it cool in a 150mL beaker. Pour in 25mL of 6M H2SO4 while stirring. Aluminum hydroxide will begin to form. The next step is to heat the mixture on a hot plate until the aluminum hydroxide dissolves. When done heating filter any solids out. On the bottom of the beaker with the solution you will want to have scratched the surface. Once that is done you will stick the beaker in a tub of iced water. Crystals of alum will start to form in the next 20 minutes. To test the purity of the alum crystals, you’ll want to vacuum filter the crystals from the solution. Having the crystals on filter paper, pour two sets of 5mL 50% ethanol-water solution on it. You’ll want to then find out the mass of the crystals. To determine the melting point you’ll need to have put a small amount of the crystals into a melting point capillary. The crystals will need to be at the bottom of the tube. Attaching a thermometer to the capillary tube and inserting it into water and heating it up will allow you to determine the melting point.Observations During this experiment there were many observations that could be made. When the 25mL of 4 M KOH was added to the broken-up pieces of aluminum, the reaction produced heat and some smoke. You could feel the beaker heating up as the reaction started to bubble and turn into a nice uniformly gray color. After the reaction was done, when adding 25mL of 6 M H2SO4 and stirring it around, insoluble aluminum hydroxide formed, and it looked like a wet cotton ball. You could see the “cotton ball” dissolve in the warm water. When is was done dissolving and cooled, you were able to watch the crystals of alum form. As the crystals were heated up in water, you were able to watch it melt. Data Mass of Aluminum: 1.002g Mass of Alum Produced: 15.416g Melting Point of Alum Crystals: 83¬℃ Theoretical Yield of Alum: 17.62g Percentage Yield of Alum: 82.49% Calculations Results The result of this experiment was that 15.416g of Potassium Alum was produced. The observed melting point of the alum crystals was 83℃. The theoretical yield of alum was 17.62g, which we were just shy of by 2.20g, or 18.51%. Conclusion Concluding this experiment, we were able to successfully synthesize alum from a piece of aluminum foil. The results show we formed 15.416g of alum, 18.51% less than the maximum possible amount. Possible errors may have occurred when transferring the chemicals. When pouring into new containers, filtering, and scraping off from the filter paper, the left-over bits that were not able to be used in the entire experiment may have possibly changed the outcome of the experiment.

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